Alternating polystannanes: syntheses and properties.
نویسندگان
چکیده
A new condensation polymerization route leading to alternating polystannanes is presented. The stoichiometric reaction of tin dihydrides and tin diamides in diethyl ether or toluene under mild reaction conditions afforded three new moderate molecular weight alternating polystannanes, -[Ph2Sn-alt-Sn(n-Bu)2]n-, -[Ph2Sn-alt-SnMe2]n-, -[Me2Sn-alt-Sn(n-Bu)2]n-, in addition to a known homopolymer, -[(n-Bu)2]n-.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 33 شماره
صفحات -
تاریخ انتشار 2015